Three-dimensional forward and backward modelling of diapirism: numerical approach and its applicability to the evolution of salt structures in the Pricaspian basin     

Alik Ismail-Zadeh  Igor Tsepelev  Chistopher Talbot  Alexander Korotkii   《Tectonophysics》2004,387(1-4):81-103

Numerical studies of ductile deformations induced by salt movements have, until now, been restricted to two-dimensional (2D) modelling of diapirism. This paper suggests a numerical approach to model the evolution of three-dimensional (3D) salt structures toward increasing maturity. This approach is also used here to restore the evolution of salt structures through successive earlier stages. The numerical methodology is applied to study several model examples. We analyse a model of salt diapirs that develop from an initial random perturbation of the interface between salt and its overburden and restore the evolved salt diapirs to their initial stages. We show that the average restoration errors are less than 1%. An evolutionary model of a 2D salt wall loaded by a 2D pile of sediments predicts a decomposition of the salt wall into 3D diapiric structures when the overburden of salt is supplied by 3D synkinematic wedge of sediments. We model salt extrusion feeding a gravity current over the depositional surface and estimate an average rate of extrusion and horizontal velocity of salt spreading. Faulting of the overburden to salt overhangs initiates new secondary diapirs, and we analyse the growth of these secondary diapirs. We also study how lateral flow effects the evolution of salt diapirs. The shape of a salt diapir can be very different if the rate of horizontal flow is much greater than the initial rate of diapiric growth solely due to gravity. We discuss the applicability of the results of the models to the evolution of Late Permian salt structures in the Pricaspian basin (Russia and Kazakhstan). These structures are distinguishable into a variety of styles representing different stages of growth: salt pillows, diapirs, giant salt massifs, 2D diapiric walls and 3D stocks complicated by large overhangs. The different sizes, shapes and maturities of salt structures in different parts of the Pricaspian basin reflect areal differences in salt thickness and loading history. Our results suggest that the numerical methodology can be employed to analyse the evolution of all salt structures that have upbuilt through younger ductile overburdens.  相似文献   

SIR WILFRED THESIGER 1910–2003     

Alexander Maitland 《The Geographical journal》2004,170(1):92-94

  相似文献   

A noble record     

Alexander B Verchovsky  Mark A Sephton 《Astronomy& Geophysics》2005,46(2):2.12-2.14

Alexander B Verchovsky and Mark A Sephton review the origins and significance of noble gases in meteorites, focusing on what this unique record reveals about the early solar system.  相似文献   

Karst database development in Minnesota: design and data assembly   总被引：1，自引：0，他引：1  

Y. Gao  E. C. Alexander Jr  R. G. Tipping 《Environmental Geology》2005,47(8):1072-1082

The Karst Feature Database (KFD) of Minnesota is a relational GIS-based Database Management System (DBMS). Previous karst feature datasets used inconsistent attributes to describe karst features in different areas of Minnesota. Existing metadata were modified and standardized to represent a comprehensive metadata for all the karst features in Minnesota. Microsoft Access 2000 and ArcView 3.2 were used to develop this working database. Existing county and sub-county karst feature datasets have been assembled into the KFD, which is capable of visualizing and analyzing the entire data set. By November 17 2002, 11,682 karst features were stored in the KFD of Minnesota. Data tables are stored in a Microsoft Access 2000 DBMS and linked to corresponding ArcView applications. The current KFD of Minnesota has been moved from a Windows NT server to a Windows 2000 Citrix server accessible to researchers and planners through networked interfaces.  相似文献   

Unique Marine Olenekian-Anisian Boundary Section from South Primorye, Russian Far East     

Yuri D Zakharov Alexander M Popov Galina I Buryi 《中国地质大学学报(英文版)》2005,16(3):219-230

INTRODUCTION LateOlenekianandAnisianmarinedepositsin SouthPrimoryewerefirststudiedbyD.L.Ivanov,thechiefofageologicalteammakingreconnaissance workfortheconstructionofthetrans Siberianrail road.HecollectedEarlyandMiddleTriassicam monoidsonRussianIsland.Arep…  相似文献   

6: Classification of VMS deposits: Lessons from the South Uralides     

Richard Herrington  Valeriy Maslennikov  Victor Zaykov  Igor Seravkin  Alexander Kosarev  Bernd Buschmann  Jean-Jacques Orgeval  Nicola Holland  Svetlana Tesalina  Paolo Nimis  Robin Armstrong 《Ore Geology Reviews》2005,27(1-4):203

VMS deposits of the South Urals developed within the evolving Urals palaeo-ocean between Silurian and Late Devonian times. Arc-continent collision between Baltica and the Magnitogorsk Zone (arc) in the south-western Urals effectively terminated submarine volcanism in the Magnitogorsk Zone with which the bulk of the VMS deposits are associated. The majority of the Urals VMS deposits formed within volcanic-dominated sequences in deep seawater settings. Preservation of macro and micro vent fauna in the sulphide bodies is both testament to the seafloor setting for much of the sulphides but also the exceptional degree of preservation and lack of metamorphic overprint of the deposits and host rocks. The deposits in the Urals have previously been classified in terms of tectonic setting, host rock associations and metal ratios in line with recent tectono-stratigraphic classifications. In addition to these broad classes, it is clear that in a number of the Urals settings, an evolution of the host volcanic stratigraphy is accompanied by an associated change in the metal ratios of the VMS deposits, a situation previously discussed, for example, in the Noranda district of Canada.Two key structural settings are implicated in the South Urals. The first is seen in a preserved marginal allochthon west of the Main Urals Fault where early arc tholeiites host Cu–Zn mineralization in deposits including Yaman Kasy, which is host to the oldest macro vent fauna assembly known to science. The second tectonic setting for the South Urals VMS is the Magnitogorsk arc where study has highlighted the presence of a preserved early forearc assemblage, arc tholeiite to calc-alkaline sequences and rifted arc bimodal tholeiite sequences. The boninitc rocks of the forearc host Cu–(Zn) and Cu–Co VMS deposits, the latter hosted in fragments within the Main Urals Fault Zone (MUFZ) which marks the line of arc-continent collision in Late Devonian times. The arc tholeiites host Cu–Zn deposits with an evolution to more calc-alkaline felsic volcanic sequences matched with a change to Zn–Pb–Cu polymetallic deposits, often gold-rich. Large rifts in the arc sequence are filled by thick bimodal tholeiite sequences, themselves often showing an evolution to a more calc-alkaline nature. These thick bimodal sequences are host to the largest of the Cu–Zn VMS deposits.The exceptional degree of preservation in the Urals has permitted the identification of early seafloor clastic and hydrolytic modification (here termed halmyrolysis sensu lato) to the sulphide assemblages prior to diagenesis and this results in large-scale modification to the primary VMS body, resulting in distinctive morphological and mineralogical sub-types of sulphide body superimposed upon the tectonic association classification.It is proposed that a better classification of seafloor VMS systems is thus achievable using a three stage classification based on (a) tectonic (hence bulk volcanic chemistry) association, (b) local volcanic chemical evolution within a single edifice and (c) seafloor reworking and halmyrolysis.  相似文献   

Origin of low-Ca pyroxene in amoeboid olivine aggregates: Evidence from oxygen isotopic compositions     

Alexander N. Krot  Timothy J. Fagan  Kazuhide Nagashima  Hisayoshi Yurimoto 《Geochimica et cosmochimica acta》2005,69(7):1873-1881

Amoeboid olivine aggregates (AOAs) in primitive carbonaceous chondrites consist of forsterite (Fa_<2), Fe,Ni-metal, spinel, Al-diopside, anorthite, and rare gehlenitic melilite (Åk_<15). ∼10% of AOAs contain low-Ca pyroxene (Fs_1-3Wo_1-5) that is in corrosion relationship with forsterite and is found in three major textural occurrences: (i) thin (<15 μm) discontinuous layers around forsterite grains or along forsterite grain boundaries in AOA peripheries; (ii) 5-10-μm-thick haloes and subhedral grains around Fe,Ni-metal nodules in AOA peripheries, and (iii) shells of variable thickness (up to 70 μm), commonly with abundant tiny (3-5 μm) inclusions of Fe,Ni-metal grains, around AOAs. AOAs with the low-Ca pyroxene shells are compact and contain euhedral grains of Al-diopside surrounded by anorthite, suggesting small (10%-20%) degree of melting. AOAs with other textural occurrences of low-Ca pyroxene are rather porous. Forsterite grains in AOAs with low-Ca pyroxene have generally ¹⁶O-rich isotopic compositions (Δ¹⁷O < −20‰). Low-Ca pyroxenes of the textural occurrences (i) and (ii) are ¹⁶O-enriched (Δ¹⁷O < −20‰), whereas those of (iii) are ¹⁶O-depleted (Δ¹⁷O = −6‰ to −4‰). One of the extensively melted (>50%) objects is texturally and mineralogically intermediate between AOAs and Al-rich chondrules. It consists of euhedral forsterite grains, pigeonite, augite, anorthitic mesostasis, abundant anhedral spinel grains, and minor Fe,Ni-metal; it is surrounded by a coarse-grained igneous rim largely composed of low-Ca pyroxene with abundant Fe,Ni-metal-sulfide nodules. The mineralogical observations suggest that only spinel grains in this igneous object were not melted. The spinel is ¹⁶O-rich (Δ¹⁷O ∼ −22‰), whereas the neighboring plagioclase mesostasis is ¹⁶O-depleted (Δ¹⁷O ∼ −11‰).We conclude that AOAs are aggregates of solar nebular condensates (forsterite, Fe,Ni-metal, and CAIs composed of Al-diopside, anorthite, spinel, and ±melilite) formed in an ¹⁶O-rich gaseous reservoir, probably CAI-forming region(s). Solid or incipiently melted forsterite in some AOAs reacted with gaseous SiO in the same nebular region to form low-Ca pyroxene. Some other AOAs appear to have accreted ¹⁶O-poor pyroxene-normative dust and experienced varying degrees of melting, most likely in chondrule-forming region(s). The most extensively melted AOAs experienced oxygen isotope exchange with ¹⁶O-poor nebular gas and may have been transformed into chondrules. The original ¹⁶O-rich signature of the precursor materials of such chondrules is preserved only in incompletely melted grains.  相似文献   

Experimental and theoretical study of hydration of halide ions     

Alexander Likholyot 《Geochimica et cosmochimica acta》2005,69(12):2949-2958

We have studied thermochemistry of the first hydration steps for Cl⁻, Br⁻, and I⁻ in the gas phase both experimentally using high-pressure mass spectrometry (HPMS) and theoretically using density functional theory (DFT) calculations. The highest hydration steps measured experimentally were n = 8 for Cl⁻, n = 7 for Br⁻, and n = 5 for I⁻, all of them being higher than previously reported. Both experimental and theoretical stepwise enthalpies and entropies of hydration for these halides exhibited non-monotonic behavior for successive hydration steps that was not reported in previous HPMS investigations of these reactions. This behavior can be successfully interpreted using halide water cluster geometries obtained from DFT calculations by considering the number of additional hydrogen bonds formed at each hydration step and simultaneous weakening of ion-solvent interaction with increasing cluster size. Results of DFT calculations for surface cluster geometries agree better with experimental results than do the results for interior cluster geometries. We conclude that predominantly surface clusters were observed in our experiments and that small surface clusters have larger number of possible isomers than the interior clusters of the same size. The results for enthalpies of hydration for the studied halide ions lead to the conclusion that ion-solvent interaction is stronger than solvent-solvent interaction for chloride-water clusters. The difference between the two types of interaction diminishes with increasing anion size. The ion-solvent and solvent-solvent interactions are of nearly equal magnitude for iodide.  相似文献   

A refractory inclusion with solar oxygen isotopes and the rarity of such objects in the meteorite record     

Levke Kp  Kazuhide Nagashima  Andrew M. Davis  Alexander N. Krot 《Meteoritics & planetary science》2020,55(3):524-534

NASA's Genesis mission revealed that the Sun is enriched in ¹⁶O compared to the Earth and Mars (the Sun's Δ¹⁷O, defined as δ¹⁷O–0.52×δ¹⁸O, is –28.4 ± 3.6‰; McKeegan et al. 2011). Materials as ¹⁶O‐rich as the Sun are extremely rare in the meteorite record. Here, we describe a Ca‐Al‐rich inclusion (CAI) from a CM chondrite that is as ¹⁶O‐enriched as the Sun (Δ¹⁷O = –29.1 ± 0.7‰). This CAI also has large nucleosynthetic anomalies in ⁴⁸Ca and ⁵⁰Ti (δ‐values are –8.1 ± 3.3 and –11.7 ± 2.4‰, respectively) and shows no clear evidence for incorporation of live ²⁶Al; (²⁶Al/²⁷Al)₀ = (0.03 ± 0.11) × 10^–5. Due to their anomalous isotopic characteristics, the rare CAIs consistent with the Genesis value could be among the first materials that formed in the solar system. In contrast to the CAI studied here, the majority of CAIs formed in or interacted with a reservoir characterized by a Δ¹⁷O value near –23.5‰. Combined with ²⁶Al‐²⁶Mg systematics, the oxygen isotopic compositions of FUN (fractionation and unidentified nuclear effects), UN, and normal CAIs suggest that nebular conditions were favorable for solids to inherit this value for an extended period of time. Many later‐formed materials, such as chondrules, planetesimals, and terrestrial planets, formed in reservoirs with Δ¹⁷O near 0‰. The distribution could be easier to explain if the common CAI value of –23.5‰, which is consistent with the Genesis value within 3σ, represented the average composition of the protoplanetary disk.  相似文献   

High‐temperature gold‐copper extraction with chloride flux in lava tubes of Tolbachik volcano (Kamchatka)     

Vadim S. Kamenetsky  Alexander Belousov  Victor V. Sharygin  Liudmila M. Zhitova  Kathy Ehrig  Michael E. Zelenski  Ilya Chaplygin  Marina A. Yudovskaya  Pavel N. Nesterenko  Sergey M. Zakharov 《地学学报》2019,31(6):511-517

Subvolcanic environments in supra‐subduction zones are renowned for hosting epithermal deposits that often contain electrum and native gold, including bonanza examples. This study examined mineral assemblages and processes occurring in shallow‐crust volcanic settings using recent eruption (2012–2013) of the basaltic Tolbachik volcano in the Kamchatka arc. The Tolbachik eruptive system is characterized by an extensive system of lava tubes. After cessation of magma input, the tubes maintained the flow of hot oxidized gases that episodically interacted with the lava surfaces and sulphate‐chloride precipitates from volcanic gases on these surfaces. The gas‐rock interaction had strong pyrometamorphic effects that resulted in the formation of molten salt, oxidized (tenorite, hematite, Cu‐rich magnesioferrite) and skarn‐like silicate mineral assemblages. By analogy with experimental studies, we propose that a combination of these processes was responsible for extraction of metals from the basaltic wall rocks and deposition of Cu‐, Fe‐ and Cu‐Fe‐oxides and native gold.  相似文献